Chloroform has $\Delta H_{vaporization} = 29.2 \ kJ/mol$ and boils at $61.2 \ ^oC$. What is the value of $\Delta S_{vaporization}$ for chloroform? $...... \ J/mol \ K$

  • A
    $87.3$
  • B
    $477.1$
  • C
    $-87.3$
  • D
    $-477.1$

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The standard enthalpies of formation of $1,3-butadiene(g)$,$CO_{2(g)}$,and $H_2O_{(l)}$ at $298 \ K$ are $-30$,$-94$,and $-68 \ kcal/mol$ respectively. If the magnitude of resonance enthalpies of $1,3-butadiene$ and $CO_2$ are $10$ and $20 \ kcal/mol$ respectively,the enthalpy of combustion of $1,3-butadiene(g)$ at $298 \ K$ is $........ \ kcal/mol$. (Enthalpy of vaporization of $H_2O_{(l)}$ at $298 \ K = 10 \ kcal/mol$)

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Which of the following relations are correct?
$(A)$ $\Delta U = q + p \Delta V$
$(B)$ $\Delta G = \Delta H - T \Delta S$
$(C)$ $\Delta S = \frac{q_{rev}}{T}$
$(D)$ $\Delta H = \Delta U - \Delta nRT$
Choose the most appropriate answer from the options given below:

Match the following processes with their corresponding entropy changes:
Process Entropy Change
$(a)$ Liquid to vapor conversion $(1)$ $\Delta S = 0$
$(b)$ Process not spontaneous at any temperature $(2)$ $\Delta S = (+)$
$(c)$ Reversible expansion of an ideal gas $(3)$ $\Delta S = (-)$

The values of $\Delta H$ for the combustion of ethene and ethyne are $-341.1 \ kcal$ and $-310.0 \ kcal$ respectively. Which of the following is a better fuel?

One mole of an ideal monoatomic gas undergoes two reversible processes ($A \rightarrow B$ and $B \rightarrow C$) as shown in the given figure:
$A \rightarrow B$ is an adiabatic process. If the total heat absorbed in the entire process ($A \rightarrow B$ and $B \rightarrow C$) is $R T_2 \ln 10$,the value of $2 \log V_3$ is . . . . . [Use,molar heat capacity of the gas at constant pressure,$C_{p, m} = \frac{5}{2} R$ ]

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