Consider the following data:
Heat of combustion of $H_{2(g)} = -241.8 \ kJ \ mol^{-1}$
Heat of combustion of $C_{(s)} = -393.5 \ kJ \ mol^{-1}$
Heat of combustion of $C_2H_5OH_{(l)} = -1234.7 \ kJ \ mol^{-1}$
The heat of formation of $C_2H_5OH_{(l)}$ is $(-)$ $...... \ kJ \ mol^{-1}$ (Nearest integer).

Comment on the thermodynamic stability of $NO_{(g)}$,given:
$\frac{1}{2} N_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{(g)}; \Delta_r H^{\ominus} = 90 \, kJ \, mol^{-1}$
$NO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow NO_{2(g)}; \Delta_r H^{\ominus} = -74 \, kJ \, mol^{-1}$

What will be the $C-H$ bond enthalpy if:
$CH_{4(g)} + 2O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)};$ $\Delta H = -890 \, kJ$
$CO_{2(g)} \rightarrow C_{(graphite)} + O_{2(g)};$ $\Delta H = 393 \, kJ$
$2H_2O_{(l)} \rightarrow 2H_{2(g)} + O_{2(g)};$ $\Delta H = 571 \, kJ$
$2H_{2(g)} \rightarrow 4H_{(g)};$ $\Delta H = 871 \, kJ$
$C_{(graphite)} \rightarrow C_{(g)};$ $\Delta H = 716 \, kJ$

The bond dissociation energy of molecules is.......

Molar enthalpy of combustion of $C_2H_{2(g)}$,$C_{(s)}$,and $H_{2(g)}$ are $-1300$,$-394$,and $-286 \ kJ/mol$ respectively. The standard enthalpy of formation of $C_2H_{2(g)}$ is $:$

The heat of formation of methane $C_{(s)} + 2H_{2(g)} \to CH_{4(g)}$ at constant pressure is $-18500 \ cal$ at $25 \ ^oC$. The heat of reaction at constant volume would be (in $cal$)