Consider the following sequence of reactions:
$M^{2+}(aq.)$ $\xrightarrow{NH_4Cl(s) + (NH_4)_2CO_3 \, sol.} Q \downarrow$ $\xrightarrow[\text{Followed by addition of } (NH_4)_2C_2O_4]{CH_3COOH} R \downarrow$
Which of the following cations can form precipitate $Q$ but does not form precipitate $R$?

  • A
    $Mg^{2+}(aq.)$
  • B
    $Ca^{2+}(aq.)$
  • C
    $Sr^{2+}(aq.)$
  • D
    $Ba^{2+}(aq.)$

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Difficult
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Match column-$I$ and column-$II$ with correct relation:
Column-$I$ Column-$II$
$(i)$ Blood like red colour $(a)$ $Fe_4[Fe(CN)_6]_3$
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