Class 11Chemistry8-3.Organic Chemistry : Purification and characterizationChemical analysis of organic compounds
MediumConsider the following table$-$
Column-$I$
Column-$II$
$A$. Best and latest technique for isolation,purification and separation of organic compounds
$i$. Chromatography
$B$. In Lassaigne's test for $N$
$ii$. Vacuum distillation
$C$. In Lassaigne's test for $S$
$iii$. Violet coloured complex is formed
$D$. Aniline is separated from water by
$iv$. Prussian blue coloured complex is formed
$E$. Glycerol is purified from spent lye
$v$. Steam distillation
The correct match is$-$
| Column-$I$ | Column-$II$ |
|---|---|
| $A$. Best and latest technique for isolation,purification and separation of organic compounds | $i$. Chromatography |
| $B$. In Lassaigne's test for $N$ | $ii$. Vacuum distillation |
| $C$. In Lassaigne's test for $S$ | $iii$. Violet coloured complex is formed |
| $D$. Aniline is separated from water by | $iv$. Prussian blue coloured complex is formed |
| $E$. Glycerol is purified from spent lye | $v$. Steam distillation |
The correct match is$-$
- A$A-i, B-iv, C-iii, D-v, E-ii$
- B$A-iv, B-v, C-iii, D-ii, E-i$
- C$A-i, B-iv, C-iii, D-v, E-ii$
- D$A-v, B-iii, C-iv, D-ii, E-i$
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Similar Questions
In a Lassaigne's test for sulphur in an organic compound,the purple colour formed with sodium nitroprusside solution is due to the formation of:
Medium
View SolutionThe Kjeldahl's method for the estimation of nitrogen can be used to estimate the amount of nitrogen in which one of the following compounds?
Match the organic compounds in column $I$ with the Lassaigne's test results in column $II$ appropriately.
Column $I$ Column $II$ $A$. Aniline $i$. Red colour with $FeCl_3$ $B$. Benzene sulfonic acid $ii$. Violet colour with sodium nitroprusside $C$. Thiourea $iii$. Blue colour with hot and acidic solution of $FeSO_4$
| Column $I$ | Column $II$ |
|---|---|
| $A$. Aniline | $i$. Red colour with $FeCl_3$ |
| $B$. Benzene sulfonic acid | $ii$. Violet colour with sodium nitroprusside |
| $C$. Thiourea | $iii$. Blue colour with hot and acidic solution of $FeSO_4$ |
DifficultJEE MAIN 2015
View SolutionIn $Lassaigne's$ test,the organic compound is fused with $Na$ metal followed by extraction with distilled water. Which of the following is not a possible product of this fusion reaction?
Easy
View SolutionMatch the compounds in Column $I$ with their characteristic test$(s)$ reaction$(s)$ given in Column $II$.
Column $I$ Column $II$ $A. H_2N-NH_3^+Cl^-$ $p. \text{Sodium fusion extract of the compound gives Prussian blue colour with } FeSO_4$ $B. HO-C_6H_4-CH(NH_3^+)COOH \text{ (with } I^- \text{ counterion)}$ $q. \text{Gives positive } FeCl_3 \text{ test}$ $C. HO-C_6H_4-NH_3^+Cl^-$ $r. \text{Gives white precipitate with } AgNO_3$ $D. (NO_2)_2C_6H_3-NH-NH_3^+Br^-$ $s. \text{Reacts with aldehydes to form the corresponding hydrazone derivative}$
| Column $I$ | Column $II$ |
|---|---|
| $A. H_2N-NH_3^+Cl^-$ | $p. \text{Sodium fusion extract of the compound gives Prussian blue colour with } FeSO_4$ |
| $B. HO-C_6H_4-CH(NH_3^+)COOH \text{ (with } I^- \text{ counterion)}$ | $q. \text{Gives positive } FeCl_3 \text{ test}$ |
| $C. HO-C_6H_4-NH_3^+Cl^-$ | $r. \text{Gives white precipitate with } AgNO_3$ |
| $D. (NO_2)_2C_6H_3-NH-NH_3^+Br^-$ | $s. \text{Reacts with aldehydes to form the corresponding hydrazone derivative}$ |
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