Consider the reaction:
$Cl_{2(aq)} + H_2S_{(aq)} \rightarrow S_{(s)} + 2H^{+}_{(aq)} + 2Cl^{-}_{(aq)}$
The rate equation for this reaction is:
$\text{rate} = k[Cl_2][H_2S]$
Which of these mechanisms is/are consistent with this rate equation?
$A.$ $Cl_2 + H_2S \rightarrow H^{+} + Cl^{-} + Cl^{+} + HS^{-}$ (slow)
$Cl^{+} + HS^{-} \rightarrow H^{+} + Cl^{-} + S$ (fast)
$B.$ $H_2S \rightleftharpoons H^{+} + HS^{-}$ (fast equilibrium)
$Cl_2 + HS^{-} \rightarrow 2Cl^{-} + H^{+} + S$ (slow)

  • A
    $B$ only
  • B
    Both $A$ and $B$
  • C
    Neither $A$ nor $B$
  • D
    $A$ only

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For the reaction $Cl_{2(aq)} + H_2S_{(aq)} \to S_{(s)} + 2H^{+}_{(aq)} + 2Cl^{-}_{(aq)}$,the rate law is $r = K[Cl_2][H_2S]$. Which of the following mechanisms is/are consistent with this rate law?
$A. \ H_2S \rightleftharpoons H^{+} + HS^{-}$ (fast)
$Cl_2 + HS^{-} \to 2Cl^{-} + H^{+} + S$ (slow)
$B. \ Cl_2 + H_2S \to H^{+} + Cl^{-} + Cl^{+} + HS^{-}$ (slow)
$Cl^{+} + HS^{-} \to H^{+} + Cl^{-} + S$ (fast)

The reaction $2FeCl_3 + SnCl_2 \to 2FeCl_2 + SnCl_4$ is an example of

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