Consider the reaction $X \rightleftharpoons Y$ at $300 \text{ K}$. If $\Delta H^\circ$ and $K$ are $28.40 \text{ kJ mol}^{-1}$ and $1.8 \times 10^{-7}$ at the same temperature, then the magnitude of $\Delta S^\circ$ for the reaction in $\text{J K}^{-1} \text{ mol}^{-1}$ is . . . . . . . (Nearest integer) (Given: $R = 8.3 \text{ J K}^{-1} \text{ mol}^{-1}$, $\ln 10 = 2.3$, $\log 3 = 0.48$, $\log 2 = 0.30$)

  • A
    $50$
  • B
    -$50$
  • C
    $25$
  • D
    -$25$

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The reaction,$CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$ is in equilibrium in a closed vessel at $298 \, K$. The partial pressure (in $atm$) of $CO_{2(g)}$ in the reaction vessel is closest to $....$ [Given : The change in Gibbs energies of formation at $298 \, K$ and $1 \, bar$ for $CaO_{(s)} = -603.501 \, kJ \, mol^{-1}$,$CO_{2(g)} = -394.389 \, kJ \, mol^{-1}$,$CaCO_{3(s)} = -1128.79 \, kJ \, mol^{-1}$,Gas constant,$R = 8.314 \, J \, K^{-1} \, mol^{-1}$]

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In the glycolysis process,during the phosphorylation of glucose,the equilibrium constant at $298 \ K$ is $3.6 \times 10^{-3}$. Find the value of $\Delta G^{\Theta}$. What does this indicate? $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$

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