Consider the reaction between chlorine and nitric oxide:
$Cl_{2(g)} + 2NO_{(g)} \rightarrow 2NOCl_{(g)}$
On doubling the concentration of both reactants,the rate of the reaction increases by a factor of $8$. However,if only the concentration of $Cl_2$ is doubled,the rate increases by a factor of $2$. The order of this reaction with respect to $NO$ is :

  • A
    $0$
  • B
    $1$
  • C
    $2$
  • D
    $3$

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For the reaction $2A + B \rightarrow C + D$,select the correct rate law based on the following data:
$1$. $[A] = 0.1, [B] = 0.1, \text{Initial Rate} = 7.5 \times 10^{-3}$
$2$. $[A] = 0.3, [B] = 0.2, \text{Initial Rate} = 9.0 \times 10^{-2}$
$3$. $[A] = 0.3, [B] = 0.4, \text{Initial Rate} = 3.6 \times 10^{-1}$
$4$. $[A] = 0.4, [B] = 0.1, \text{Initial Rate} = 3.0 \times 10^{-2}$

If the rate law of a reaction $n A \rightarrow B$ is expressed as Rate $= -\frac{1}{n} \frac{d[A]}{dt} = \frac{d[B]}{dt} = k[A]^{x}$,the unit of rate constant $k$ will be:

$A$ reaction is first order in $A$ and second order in $B$.
$(i)$ Write the differential rate equation.
$(ii)$ How is the rate affected on increasing the concentration of $B$ three times?
$(iii)$ How is the rate affected when the concentrations of both $A$ and $B$ are doubled?

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Write the unit of the rate constant for the following reactions:
$1.$ Zero order
$2.$ Second order

The decomposition of dimethyl ether leads to the formation of $CH_4$,$H_2$ and $CO$ and the reaction rate is given by
Rate $= k [CH_3OCH_3]^{3/2}$
The rate of reaction is followed by increase in pressure in a closed vessel,so the rate can also be expressed in terms of the partial pressure of dimethyl ether,i.e.
Rate $= k (p_{CH_3OCH_3})^{3/2}$
If the pressure is measured in $bar$ and time in $minutes$,then what are the units of rate and rate constants?

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