Consider the reactions:
$2S_2O_3^{2-}{(aq)} + I_{2(s)} \to S_4O_6^{2-}{(aq)} + 2I^{-}{(aq)}$
$S_2O_3^{2-}{(aq)} + 2Br_{2(l)} + 5H_2O_{(l)} \to 2SO_4^{2-}{(aq)} + 4Br^{-}{(aq)} + 10H^{+}{(aq)}$
Why does the same reductant,thiosulphate,react differently with iodine and bromine?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The average oxidation number $(O.N.)$ of $S$ in $S_2O_3^{2-}$ is $+2$.
$Br_2$ is a stronger oxidizing agent than $I_2$.
$Br_2$ oxidizes the sulfur in thiosulfate to the $+6$ oxidation state (in $SO_4^{2-}$).
$I_2$ is a weaker oxidizing agent and can only oxidize the sulfur to an average oxidation state of $+2.5$ (in $S_4O_6^{2-}$).
Therefore,the extent of oxidation depends on the strength of the oxidizing agent,causing the thiosulfate to react differently.

Explore More

Similar Questions

If stoichiometric quantities of a $KMnO_4$ and $K_2Cr_2O_7$ mixture are added for the oxidation of $Fe^{2+}$ to $Fe^{3+}$ in an acidic medium,then $Fe^{2+}$ will be oxidized:

In neutral or faintly alkaline medium,$MnO_4^{-}$ oxidizes $I^{-}$ to iodate. What is the volume (in $L$) of $0.02 \ M \ KMnO_4$ required to completely convert $1 \ L$ of $0.5 \ M \ KI$ solution to iodate in neutral or faintly alkaline medium?

Which of the following shows a metal being oxidised?

In which of the following reactions, chlorine acts as an oxidising agent?
$(i)$ $CH_3CH_2OH + Cl_2 \longrightarrow CH_3CHO + HCl$
(ii) $CH_3CHO + Cl_2 \longrightarrow CCl_3CHO + HCl$
(iii) $CH_4 + Cl_2 \stackrel{hv}{\longrightarrow} CH_3Cl + HCl$
The correct answer is

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$Ca(OH)_2 + CO_2 \longrightarrow CaCO_3 \downarrow + H_2O$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo