Consider the reactions:
$C_{(s)} + 2H_{2(g)} \to CH_{4(g)}, \Delta H = -x \ kcal$
$C_{(g)} + 4H_{(g)} \to CH_{4(g)}, \Delta H = -x_1 \ kcal$
$CH_{4(g)} \to CH_{3(g)} + H_{(g)}, \Delta H = +y \ kcal$
The bond energy of $C-H$ bond is:

  • A
    $y \ kcal \ mol^{-1}$
  • B
    $x_1 \ kcal \ mol^{-1}$
  • C
    $x/4 \ kcal \ mol^{-1}$
  • D
    $x_1/4 \ kcal \ mol^{-1}$

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The bond enthalpies of $H_2$,$X_2$,and $HX$ are in the ratio of $2 : 1 : 2$. If the standard enthalpy of formation of $HX$ is $-50 \ kJ \ mol^{-1}$,the bond enthalpy of $H_2$ is .... $kJ \ mol^{-1}$.

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If the bond energies of $H-H$,$Br-Br$ and $H-Br$ are $433$,$192$ and $364 \ kJ \ mol^{-1}$ respectively,then $\Delta H^{\circ}$ for the reaction: $H_{2(g)} + Br_{2(g)} \rightarrow 2HBr_{(g)}$ is:

$H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}$; $\Delta H$ at $298 \ K = -285.8 \ kJ$. The molar enthalpy of vaporization of water at $1 \ atm$ and $25^{\circ}C$ is $44 \ kJ$. The standard enthalpy of formation of $1 \ mole$ of water vapor at $25^{\circ}C$ is $...... \ kJ$. (in $.8$)

Calculate the heat change for the reaction $4NH_3(g) + 3O_2(g) \rightarrow 2N_2(g) + 6H_2O(l)$ in $kJ$. The enthalpies of formation of $NH_3(g)$ and $H_2O(l)$ at $298 \ K$ are $-46.0 \ kJ \ mol^{-1}$ and $-286.0 \ kJ \ mol^{-1}$ respectively.

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