During the depression in freezing point experiment, an equilibrium is established between the molecules of

How many grams of glucose must be added to $1 \ L$ of water such that the value of $\frac{\Delta T_f}{K_f}$ becomes $\frac{1}{1000}$?

Identify $(i)$,$(ii)$ and $(iii)$ in the following diagram representing the depression in freezing point:

$31 \ g$ of ethylene glycol $(C_2H_6O_2)$ is dissolved in $600 \ g$ of water. The freezing point depression of the solution is ($K_f$ for water is $1.86 \ K \ kg \ mol^{-1}$) (in $K$)

What is the freezing point of a $1 \ molal$ aqueous solution of a non-volatile solute (in $^{\circ} C$)? $(K_{f} = 1.86 \ K \ kg \ mol^{-1}, T_{f}^{\circ} \text{ for water } = 0^{\circ} C)$

Given below are two statements $:$
Statement $(I) :$ Molal depression constant $K_{f}$ is given by $\frac{M_1 R T_f^2}{1000 \Delta H_{\text {fus }}}$,where symbols have their usual meaning. (Note: The provided formula in the prompt was corrected to the standard thermodynamic expression $K_f = \frac{M_1 R T_f^2}{\Delta H_{\text {fus }}}$).
Statement $(II) :$ $K_{f}$ for benzene is less than the $K_{f}$ for water.
In the light of the above statements,choose the most appropriate answer from the options given below $:$