During which of the following processes does entropy decrease?

The entropy change involved in the conversion of $1 \, \text{mole}$ of liquid water at $373 \, K$ to vapour at the same temperature will be $[\Delta H_{vap} = 2.257 \, kJ/g]$. (in $, kJ/K$)

At $1 \ atm$ pressure,if $\Delta S_{\text{vap}} = 75 \ J \ K^{-1} \ mol^{-1}$ and $\Delta H_{\text{vap}} = 30 \ kJ \ mol^{-1}$,what will be the boiling point of the liquid in $K$?

The standard entropies of $CO_{2(g)}$,$C_{(s)}$,and $O_{2(g)}$ are $213.5$,$5.740$,and $205 \ J \ K^{-1} \ mol^{-1}$ respectively. The standard entropy of formation of $CO_{2(g)}$ is $...... \ J \ K^{-1} \ mol^{-1}$.

For a process to occur spontaneously,

The entropy change when $2 \, \text{moles}$ of an ideal monoatomic gas is heated from $200 \, ^\circ \text{C}$ to $300 \, ^\circ \text{C}$ isochorically is: