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Which of the following is not correctly matched?

Impurities of lead in silver are removed by

Which of the following methods is used for the refining of impure zirconium?

Which method of purification is represented by the equation
$Ti + 2I_2$ (Impure) $\xrightarrow{500 \ K} TiI_4$ $\xrightarrow{1675 \ K} Ti + 2I_2$ (Pure)

Which method of refining nickel is represented by the following equation?
$Ni$ (impure) $+ 4CO$ $\xrightarrow{320 \ K} Ni(CO)_4$ $\xrightarrow{420 \ K} Ni$ (pure) $+ 4CO$

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