Enthalpy of formation of $HF$ and $HCl$ are $-161 \ kJ$ and $-92 \ kJ$ respectively. Which of the following statements is incorrect?

  • A
    $HCl$ is more stable than $HF$
  • B
    $HF$ and $HCl$ are exothermic compounds
  • C
    The affinity of fluorine to hydrogen is greater than the affinity of chlorine to hydrogen
  • D
    $HF$ is more stable than $HCl$

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The molar heat of neutralization of $NaOH$ with $HCl$ in comparison to that of $KOH$ with $HNO_3$ is:

Calculate $\Delta H^{\circ}$ for the reaction, $Na_2O_{(s)} + SO_{3(g)} \longrightarrow Na_2SO_{4(s)}$, given the following reactions:
$(A) \ Na_{(s)} + H_2O_{(l)} \longrightarrow NaOH_{(s)} + \frac{1}{2}H_{2(g)} \quad \Delta H^{\circ} = -146 \ kJ$
$(B) \ Na_2SO_{4(s)} + H_2O_{(l)} \longrightarrow 2NaOH_{(s)} + SO_{3(g)} \quad \Delta H^{\circ} = +418 \ kJ$
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If $1 \ mole$ of aqueous nitric acid is formed,calculate the total heat released based on the following reactions:
Reaction$\Delta H \ (kJ)$
$(i) \ 4NH_{3(g)} + 5O_{2(g)} \to 4NO_{(g)} + 6H_2O_{(l)}$$-904$
$(ii) \ 2NO_{(g)} + O_{2(g)} \to 2NO_{2(g)}$$-112$
$(iii) \ 3NO_{2(g)} + H_2O_{(l)} \to 2HNO_{3(aq)} + NO_{(g)}$$-140$

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Match the transformations in Column-$I$ with the appropriate options in Column-$II$.
Column-$I$ Column-$II$
$(A) \; CO_{2(s)} \to CO_{2(g)}$ $(p) \; \text{Transition state}$
$(B) \; CaCO_{3(s)} \to CaO_{(s)} + CO_{2(g)}$ $(q) \; \text{Allotropic change}$
$(C) \; 2H^{\cdot} \to H_{2(g)}$ $(r) \; \Delta H > 0$
$(D) \; P_{\text{(white solid)}} \to P_{\text{(red solid)}}$ $(s) \; \Delta S > 0$
$(t) \; \Delta S < 0$

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One mole of an ideal monoatomic gas undergoes two reversible processes ($A \rightarrow B$ and $B \rightarrow C$) as shown in the given figure:
$A \rightarrow B$ is an adiabatic process. If the total heat absorbed in the entire process ($A \rightarrow B$ and $B \rightarrow C$) is $R T_2 \ln 10$,the value of $2 \log V_3$ is . . . . . [Use,molar heat capacity of the gas at constant pressure,$C_{p, m} = \frac{5}{2} R$ ]

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