Enthalpy of sublimation of a substance is equal to

Given that the bond energy of hydrogen-hydrogen bond is $436 \ kJ/mol$,that of hydrogen-oxygen bond is $464 \ kJ/mol$,and those in oxygen molecules $496 \ kJ/mol$,what is the approximate heat of reaction for $2H_2 + O_2 \longrightarrow 2H_2O$ ? .....$kJ/mol$

Given:
$(I) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}; \Delta H^o_{298\ K} = -285.9 \ kJ \ mol^{-1}$
$(II) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(g)}; \Delta H^o_{298\ K} = -241.8 \ kJ \ mol^{-1}$
The molar enthalpy of vaporisation of water will be $kJ \ mol^{-1}$.

On the basis of the thermochemical equations:
$H_{2}O_{(g)} + C_{(s)} \to CO_{(g)} + H_{2(g)} \quad \Delta H = 131 \ kJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)} \quad \Delta H = -282 \ kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_{2}O_{(g)} \quad \Delta H = -242 \ kJ$
$C_{(s)} + O_{2(g)} \to CO_{2(g)} \quad \Delta H = X \ kJ$
The value of $X$ will be $.... \ kJ$.

Calculate the heat of combustion (in $kJ$) of methane from the following data:
$(i)$ $C_{\text{(graphite)}} + 2H_{2(g)} \rightarrow CH_{4(g)} \quad \Delta H = -74.8 \ kJ$
(ii) $C_{\text{(graphite)}} + O_{2(g)} \rightarrow CO_{2(g)} \quad \Delta H = -393.5 \ kJ$
(iii) $H_{2(g)} + 1/2 O_{2(g)} \rightarrow H_2O_{(l)} \quad \Delta H = -286.2 \ kJ$

The standard heats of formation in $kcal \ mol^{-1}$ of $NO_{2(g)}$ and $N_2O_{4(g)}$ are $8.0$ and $2.0$ respectively. The heat of dimerization of $NO_2$ in $kcal$ for the reaction $2NO_{2(g)} \rightarrow N_2O_{4(g)}$ is: