Explain the Law of Definite Proportions with examples.

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(N/A) The Law of Definite Proportions was proposed by the French chemist $Joseph \ Proust$. He stated that a given chemical compound always contains exactly the same proportion of elements by weight,regardless of its source or method of preparation.
$Proust$ worked with two samples of cupric carbonate $(CuCO_3)$—one of natural origin and the other synthetic. He found that the composition of elements present in both samples was identical,as shown in the table below:
Sample Type $\% \text{ of Copper}$ $\% \text{ of Carbon}$ $\% \text{ of Oxygen}$
Natural sample $51.35$ $9.74$ $38.91$
Synthetic sample $51.35$ $9.74$ $38.91$

Thus,irrespective of the source,a given compound always contains the same elements in the same proportion by mass. This law is also known as the Law of Definite Composition.

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Zinc sulphate contains $22.65\%$ of zinc and $43.9\%$ of water of crystallization. If the law of constant proportions is true,then the weight of zinc required to produce $20\, g$ of the crystals will be ............. $g$.

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Ammonia contains $82.35\%$ nitrogen and $17.65\%$ hydrogen. Water contains $88.90\%$ oxygen and $11.10\%$ hydrogen. Nitrogen dioxide contains $63.15\%$ oxygen and $36.85\%$ nitrogen. Which law can be illustrated by the given data?

The law of multiple proportions was proposed by

Identify the law for which the following statement is true.
"Equal volume of all gases at same temperature and pressure should contain equal number of molecules".

Match the laws given in List-$A$ with the scientists who discovered them in List-$B$.
List-$A$ List-$B$
$(1)$ Law of Multiple Proportions $(A)$ Dalton
$(2)$ Law of Conservation of Mass $(B)$ Joseph Proust
$(3)$ Law of Definite Proportions $(C)$ Lavoisier
$(D)$ Hofmann

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