For $Cr_2O_7^{2-} + 14H^{+} + 6e^- \longrightarrow 2Cr^{3+} + 7H_2O$,$E^0 = 1.33 \ V$. Given $[Cr_2O_7^{2-}] = 4.5 \ mmol$,$[Cr^{3+}] = 1.5 \ mmol$ and $E = 1.067 \ V$,calculate the $pH$ of the solution.

What is the potential of a hydrogen electrode in contact with a solution whose $pH$ is $1$ (in $V$)?

Calculate the potential of a hydrogen electrode in contact with a solution whose $pH = 10$.

Which of the following expressions indicates the correct relationship between molar conductivity of a strong electrolyte and its concentration $c$?

For the electrochemical cell shown below:
$Pt \mid H_{2}(p=1 \, atm) \mid H^{+}(aq., x \, M) \mid\mid Cu^{2+}(aq., 1.0 \, M) \mid Cu_{(s)}$
The potential is $0.49 \, V$ at $298 \, K$. The $pH$ of the solution is closest to:
[Given: Standard reduction potential,$E^{\circ}$ for $Cu^{2+}/Cu$ is $0.34 \, V$; Gas constant,$R = 8.31 \, J \, K^{-1} \, mol^{-1}$; Faraday constant,$F = 9.65 \times 10^{4} \, J \, V^{-1} \, mol^{-1}$]

The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. $A$ simple model for such a concentration cell involving a metal $M$ is:
$M_{(s)} \mid M^{+}(aq; 0.05 \ M) \parallel M^{+}(aq; 1 \ M) \mid M_{(s)}$
For the above electrolytic cell the magnitude of the cell potential $|E_{cell}|=70 \ mV$.
$1.$ For the above cell
$(A)$ $E_{cell} < 0 ; \Delta G > 0$ $(B)$ $E_{cell} > 0 ; \Delta G < 0$
$(C)$ $E_{cell} < 0 ; \Delta G^{\circ} > 0$ $(D)$ $E_{cell} > 0 ; \Delta G^{\circ} > 0$
$2.$ If the $0.05 \ M$ solution of $M^{+}$ is replaced by $0.0025 \ M$ $M^{+}$ solution,then the magnitude of the cell potential would be
$(A)$ $35 \ mV$ $(B)$ $70 \ mV$ $(C)$ $140 \ mV$ $(D)$ $700 \ mV$
Give the answer for questions $1$ and $2$.