For a chemical reaction,$2A + 2B \to C + D$,the order of reaction is $1$ with respect to $A$ and $1$ with respect to $B$. The initial rate of the reaction is $4 \times 10^{-2} \ mol \ L^{-1} \ s^{-1}$. When $50\%$ of the reactants are converted into products,the rate of the reaction would become:

  • A
    $2 \times 10^{-2} \ mol \ L^{-1} \ s^{-1}$
  • B
    $1 \times 10^{-2} \ mol \ L^{-1} \ s^{-1}$
  • C
    $4 \times 10^{-2} \ mol \ L^{-1} \ s^{-1}$
  • D
    $2 \times 10^{-1} \ mol \ L^{-1} \ s^{-1}$

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The rate constant value for a reaction is $1.75 \times 10^2 \ L^2 \ mol^{-2} \ sec^{-1}$. The half-life period $t_{1/2} \propto$ . . . . . . .

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$Expt.$ $[X]_0 / mol \ L^{-1}$ $[Y]_0 / mol \ L^{-1}$ $Rate / mol \ L^{-1} s^{-1}$
$1$ $0.25$ $0.25$ $1.0 \times 10^{-6}$
$2$ $0.50$ $0.25$ $4.0 \times 10^{-6}$
$3$ $0.25$ $0.50$ $8.0 \times 10^{-6}$

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