For a chemical reaction, half-life period $(t_{1/2})$ is $10 \ minutes$. How much reactant will be left after $20 \ minutes$ if one starts with $100 \ moles$ of reactant and the order of the reaction is $(i)$ zero, $(ii)$ one, and $(iii)$ two?

  • A
    $0, 25, 33.33$
  • B
    $25, 0, 33.33$
  • C
    $33.33, 25, 0$
  • D
    $25, 33.33, 0$

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Write equations of the following:
$(i)$ The integrated rate equation for a zero-order reaction.
$(ii)$ The integrated rate equation for a first-order reaction.

$A$ substance $S$ undergoes two reactions under similar reaction conditions:
$\mathop S\limits_{(2.0 \ M)} \xrightarrow{K_0} X$ (zero order)
$\mathop S\limits_{(2.0 \ M)} \xrightarrow{K_2} Y$ (second order)
The time taken for the concentration of $S$ to become half is $40 \ s$ and $10 \ s$ for the zero-order and second-order reactions,respectively. What is the value of the ratio $K_0 / K_2$?

Which of the following relations is correct for the given reaction orders?

The decomposition of $N_2O_5$ follows first-order kinetics: $N_2O_5 \rightarrow 2NO_2 + \frac{1}{2} O_2$. Its half-life is $2.4 \ hours$. If $10.8 \ g$ of $N_2O_5$ is taken initially,how many liters of $O_2$ will be obtained at $STP$ after $9.6 \ hours$?

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The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two-step process shown below:
$O_{3(g)} + Cl_{(g)}^{\bullet} \to O_{2(g)} + ClO_{(g)}^{\bullet}$ ..... $(i)$ $K_i = 5.2 \times 10^9 \ L \ mol^{-1} \ s^{-1}$
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The closest rate constant for the overall reaction
$O_{3(g)} + O_{(g)}^{\bullet} \to 2O_{2(g)}$ is ........... $L \ mol^{-1} \ s^{-1}$

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