For a chemical reaction,if the temperature is increased from $25\,^{\circ}C$ to $55\,^{\circ}C$,the rate of reaction will change by a factor of (Assume $\mu = 3$).

  • A
    $27$
  • B
    $9$
  • C
    $3$
  • D
    $2$

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Consider the following transformation involving first order elementary reactions in each step at constant temperature as shown below.
$A + B \underset{\text{Step } 3}{\overset{\text{Step } 1}{\rightleftharpoons}} C \xrightarrow{\text{Step } 2} P$
Some details of the above reaction are listed below.
Step Rate constant $(s^{-1})$ Activation energy $(kJ \ mol^{-1})$
$1$ $k_1$ $300$
$2$ $k_2$ $200$
$3$ $k_3$ $Ea_3$

If the overall rate constant of the above transformation $(k)$ is given as $k = \frac{k_1 k_2}{k_3}$ and the overall activation energy $(E_a)$ is $400 \ kJ \ mol^{-1}$,then the value of $Ea_3$ is $\qquad$ $kJ \ mol^{-1}$ (nearest integer).

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