For a chemical reaction,the temperature is increased from $25\,^{\circ}C$ to $55\,^{\circ}C$. The rate of reaction will change by a factor of (Assume $\mu = 3$).

Match the column $I$ with column $II$ :

$a$. Rate constant for first order reaction	$i$. $mol \ lit^{-1} \sec^{-1}$
$b$. Molarity	$ii$. $\frac{k \times 1000}{M}$
$c$. Rate constant for zero order reaction	$iii$. $second^{-1}$
$d$. Limiting molar conductivity	$iv$. $\frac{\text{moles of solute}}{\text{Volume of solution (lit)}}$

The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two-step process shown below:
$O_{3(g)} + Cl_{(g)}^{\bullet} \to O_{2(g)} + ClO_{(g)}^{\bullet}$ ..... $(i)$ $K_i = 5.2 \times 10^9 \ L \ mol^{-1} \ s^{-1}$
$ClO_{(g)}^{\bullet} + O_{(g)}^{\bullet} \to O_{2(g)} + Cl_{(g)}^{\bullet}$ ..... $(ii)$ $K_{ii} = 2.6 \times 10^{10} \ L \ mol^{-1} \ s^{-1}$
The closest rate constant for the overall reaction
$O_{3(g)} + O_{(g)}^{\bullet} \to 2O_{2(g)}$ is ........... $L \ mol^{-1} \ s^{-1}$

Which of the following statements is correct?

Which of the following statement$(s)$ is (are) correct?

Write the half-life $({t_{1/2}})$ equation and its unit for the following reactions:
$(i)$ Zero order reaction
$(ii)$ First order reaction