For a closed circuit Daniell cell, which of the following plots is the accurate one at a given temperature?

In which metal container can an aqueous solution of $CuSO_4$ be stored?
$E^0_{Cu^{2+}/Cu} = 0.34 \ V$,$E^0_{Fe/Fe^{2+}} = 0.44 \ V$,$E^0_{Al/Al^{3+}} = 1.66 \ V$,$E^0_{Ni/Ni^{2+}} = 0.25 \ V$,$E^0_{Ag^{+}/Ag} = 0.80 \ V$

What is the decreasing order of deposition of metal on electrode if standard reduction potentials are given as: $Ag^{+} | Ag = 0.80 \ V$,$Cu^{2+} | Cu = 0.337 \ V$,$Sn^{2+} | Sn = -0.136 \ V$,$Cd^{2+} | Cd = -0.403 \ V$?

Write the equation relating thermodynamics and electrochemistry.

The standard reduction potentials of $Zn^{2+}|Zn$,$Cu^{2+}|Cu$ and $Ag^{+}|Ag$ are respectively $-0.76 \ V$,$0.34 \ V$ and $0.80 \ V$. The following cells were constructed:
$(1)$ $Zn|Zn^{2+}||Cu^{2+}|Cu$
$(2)$ $Zn|Zn^{2+}||Ag^{+}|Ag$
$(3)$ $Cu|Cu^{2+}||Ag^{+}|Ag$
What is the correct order of $E_{\text{cell}}^{\circ}$ of these cells?

$FeO_4^{2-}$ $\xrightarrow{2.2 \ V} Fe^{3+}$ $\xrightarrow{0.70 \ V} Fe^{2+}$ $\xrightarrow{-0.45 \ V} Fe^0$
$E_{FeO_4^{2-} / Fe^{2+}}^{\theta}$ is $x \times 10^{-3} \ V$. The value of $x$ is $.........$.