For a first order chemical reaction,

  • A
    the product formation rate is independent of reactant concentration.
  • B
    the time taken for the completion of half of the reaction $t_{1/2}$ is $69.3 \%$ of the rate constant $(k)$.
  • C
    the dimension of Arrhenius pre-exponential factor is reciprocal of time.
  • D
    the concentration $vs$ time plot for the reactant should be linear with a negative slope.

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The rate constant of a first-order reaction is $1.5 \times 10^7 \text{ s}^{-1}$ at $300 \text{ K}$ and $3.0 \times 10^7 \text{ s}^{-1}$ at $330 \text{ K}$. What is the activation energy $(E_a)$ for the reaction? $[R \times 2.303 = 19.15 \text{ J K}^{-1} \text{mol}^{-1}]$

For the decomposition reaction of $N_2O_5$,the slope of the graph of $\log K$ versus $1/T$ is $-1.2 \times 10^4 \ K$. Calculate the activation energy $(E_a)$ of the reaction.

The number of molecules with energy greater than the threshold energy for a reaction increases five-fold by a rise of temperature from $27^{\circ} C$ to $42^{\circ} C$. Its energy of activation in $J \ mol^{-1}$ is.............. (Take $\ln 5 = 1.6094$; $R = 8.314 \ J \ mol^{-1} K^{-1}$)

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