For a reaction $aA_{(g)} \rightleftharpoons bB_{(g)}$ at equilibrium,the heat of reaction at constant volume is $1500 \text{ cal}$ more than that at constant pressure. If the temperature is $27^\circ\text{C}$,then:

  • A
    $K_p = K_c$
  • B
    $K_p > K_c$
  • C
    $K_p < K_c$
  • D
    None of these

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$K_{p} = 0.04 \ atm$ at $899 \ K$ for the equilibrium shown below. What is the equilibrium pressure of $C_{2}H_{6}$ when it is placed in a flask at $4.0 \ atm$ pressure and allowed to come to equilibrium?
$C_{2}H_{6(g)} \longleftrightarrow C_{2}H_{4(g)} + H_{2(g)}$

At $673 \ K$,for the reaction $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$,the equilibrium constant $K_c = 0.50$. Calculate $K_p$ at this temperature. (Given $R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1}$)

Which of the following plots represent an exothermic reaction?

Explain why the partial pressure $p$ of a gas is proportional to its concentration $c$.

For the reversible reaction in equilibrium
$N_{2(g)} + O_{2(g)} \underset{k_2}{\overset{k_1}{\longleftrightarrow}} 2NO_{(g)}$
If the rate constant for the forward reaction is $k_1 = 2.1 \times 10^{-3} \ s^{-1}$ and for the backward reaction is $k_2 = 4.2 \times 10^{-4} \ s^{-1}$,then the equilibrium constant $K_c$ for the above reaction is:

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