For a reaction,$A + 2B \rightarrow$ Products,when the concentration of $B$ alone is increased,the half-life remains the same. If the concentration of $A$ alone is doubled,the rate remains the same. The unit of the rate constant for the reaction is:

  • A
    $s^{-1}$
  • B
    $L \ mol^{-1} \ s^{-1}$
  • C
    $mol \ L^{-1} \ s^{-1}$
  • D
    $atm^{-1}$

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The rate law for the reaction $A^{+} + B^{+} + C \longrightarrow \text{Product}$ is expressed as $\text{Rate} = k[A]^{2}[B]^{1}[C]^{0}$. What is the overall order of the reaction?

The data for the reaction $A + B \to C$ is given below. The rate law corresponding to the above data is:
$Exp.$ $[A]_0$ $[B]_0$ Initial rate
$(1)$ $0.012$ $0.035$ $0.10$
$(2)$ $0.024$ $0.070$ $0.80$
$(3)$ $0.024$ $0.035$ $0.10$
$(4)$ $0.012$ $0.070$ $0.80$

Why is the hydrolysis of an ester slow at the beginning and fast after some time?

The following results are obtained for the reaction $S + Nu \rightarrow \text{product}$. By which reaction mechanism does this reaction occur?
Experiment $[S]$ $[Nu]$ Rate
$1$ $0.1$ $0.1$ $2.2 \times 10^{-3}$
$2$ $0.2$ $0.1$ $4.4 \times 10^{-3}$
$3$ $0.1$ $0.2$ $4.4 \times 10^{-3}$

The rate of reaction $A + 2B \to 3C$ becomes $72$ times when the concentration of $A$ is tripled and the concentration of $B$ is doubled. The order of reaction with respect to $A$ and $B$ respectively is:

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