For combustion of one mole of magnesium in an open container at $300 \ K$ and $1 \ bar$ pressure,$\Delta_{C}H^{\ominus} = -601.70 \ kJ \ mol^{-1}$,the magnitude of change in internal energy for the reaction is $.... \ kJ$. (Nearest integer)
(Given : $R = 8.3 \ J \ K^{-1} \ mol^{-1}$ )

$A$ gas expands against a variable pressure given by $P = \frac{20}{V}$ ($P$ in $atm$ and $V$ in $L$). During expansion from volume of $1 \ L$ to $10 \ L$,the gas undergoes an increase in internal energy of $400 \ J$. How much heat is absorbed by gas during expansion (in $J$)? (Given: $1 \ L \cdot atm = 101.3 \ J$)

The $\Delta U^{\theta}$ of combustion of methane is $-X \ kJ \ mol^{-1}.$ The value of $\Delta H^{\theta}$ is

In an isobaric process,the ratio of heat supplied to the system $(dQ)$ and work done by the system $(dW)$ for a diatomic gas is:

In an adiabatic process,no transfer of heat takes place between the system and surroundings. Choose the correct option for the free expansion of an ideal gas under adiabatic conditions from the following:

$A$ piston filled with $0.04\, mol$ of an ideal gas expands reversibly from $50.0\, mL$ to $375\, mL$ at a constant temperature of $37\, ^oC$. It absorbs $208\, J$ of heat in this process. The value of $q$ and $w$ for the process will be: $(R = 8.314\, J / mol\, K)$ $(\ln 7.5 = 2.01)$