For the gas phase reaction,$PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$,which of the following conditions are correct?

  • A
    $\Delta H < 0$ and $\Delta S < 0$
  • B
    $\Delta H > 0$ and $\Delta S < 0$
  • C
    $\Delta H = 0$ and $\Delta S < 0$
  • D
    $\Delta H > 0$ and $\Delta S > 0$

Explore More

Similar Questions

The enthalpies of combustion of $S_{(s)}$ and $H_{2(g)}$ are $-300 \ kcal \ mol^{-1}$ and $-290 \ kcal \ mol^{-1}$ respectively. Given the following reactions:
$SO_{3(g)} + H_2O_{(l)} \rightarrow H_2SO_{4(l)}$; $\Delta H = -130 \ kcal \ mol^{-1}$
$SO_{2(g)} + 1/2 O_{2(g)} \rightarrow SO_{3(g)}$; $\Delta H = -100 \ kcal \ mol^{-1}$
$S_{(s)} + O_{2(g)} \rightarrow SO_{2(g)}$; $\Delta H = -300 \ kcal \ mol^{-1}$
$H_{2(g)} + 1/2 O_{2(g)} \rightarrow H_2O_{(l)}$; $\Delta H = -290 \ kcal \ mol^{-1}$
The enthalpy of formation of $H_2SO_{4(l)}$ is:

Calculate the enthalpy change when $6 \text{ g}$ of $CO(g)$ reacts with sufficient $NO_2(g)$ according to the following reaction: $4 \text{ CO}(g) + 2 \text{ NO}_2(g) \rightarrow 4 \text{ CO}_2(g) + 2 \text{ N}_2(g)$; $\Delta_r H^0 = -1200 \text{ kJ}$ (in $\text{ kJ}$)

What is the value of $\Delta S_{\text{total}}$ for the following reaction at $300 \ K$:
$Fe_{2}O_{3(s)} + 3CO_{(g)} \longrightarrow 2Fe_{(s)} + 3CO_{2(g)}$
$\Delta H^{\circ} = -25 \ kJ, \Delta S^{\circ} = 15 \ J \ K^{-1}$ (in $J \ K^{-1}$)

Match the List-$I$ with List-$II$
List-$I$ Thermodynamic Process List-$II$ Magnitude in $kJ$
$A$. Work done in reversible, isothermal expansion of $2 \ mol$ of ideal gas from $2 \ dm^3$ to $20 \ dm^3$ at $300 \ K$. $I$. $4$
$B$. Work done in irreversible isothermal expansion of $1 \ mol$ ideal gas from $1 \ m^3$ to $3 \ m^3$ at $300 \ K$ against a constant pressure of $3 \ kPa$. $II$. $11.5$
$C$. Change in internal energy for adiabatic expansion of a $1 \ mol$ ideal gas with change of temperature $= 320 \ K$ and $\overline{C}_V = \frac{3}{2} R$. $III$. $6$
$D$. Change in enthalpy at constant pressure of $1 \ mole$ ideal gas with change of temperature $= 337 \ K$ and $\overline{C}_P = \frac{5}{2} R$. $IV$. $7$

Choose the correct answer from the option given below:

Which of the following equations are correct?
$(A)$ $H = U + PV$
$(B)$ $G = H - TS$
$(C)$ $U = q + W$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo