For the given redox reaction: $a MnO_4^{-} + b S_2 O_3^{2-} + H_2 O \longrightarrow x MnO_2 + y SO_4^{2-} + z OH^-$,the values of $a$ and $y$ respectively are:

  • A
    $8; 3$
  • B
    $8; 6$
  • C
    $3; 6$
  • D
    $8; 8$

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The coefficients $x, y, p, q,$ and $r$ in the following balanced equation are respectively:
$xMnO_4^{2-}{_{\text{(aq)}}} + yH_2O_{\text{(l)}} \rightarrow pMnO_2{_{\text{(s)}}} + qMnO_4^{-}{_{\text{(aq)}}} + rOH^{-}{_{\text{(aq)}}}$

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In acidic medium,potassium dichromate acts as an oxidant according to the equation,$Cr_2O_7^{2-} + 14H^{+} + 6e^- \to 2Cr^{3+} + 7H_2O$. What is the equivalent weight of $K_2Cr_2O_7$? (Molecular weight $= M$)

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