For the reaction,$PCl_5 \longrightarrow PCl_3 + Cl_2$,the rate and rate constant are $1.02 \times 10^{-4} \ mol \ L^{-1} \ s^{-1}$ and $3.4 \times 10^{-5} \ s^{-1}$ respectively at a given instant. The molar concentration of $PCl_5$ at that instant is

  • A
    $8.0 \ mol \ L^{-1}$
  • B
    $3.0 \ mol \ L^{-1}$
  • C
    $0.2 \ mol \ L^{-1}$
  • D
    $2.0 \ mol \ L^{-1}$

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The conversion of molecules $X$ to $Y$ follows second order kinetics. If the concentration of $X$ is increased to three times,how will it affect the rate of formation of $Y$?

The reaction $A_2 + B_2 \rightarrow 2AB$ follows the mechanism $A_2 \underset{k_{-1}}{\stackrel{k_1}{\rightleftharpoons}} 2A$ (fast),$A + B_2 \xrightarrow{k_2} AB + B$ (slow),$A + B \rightarrow AB$ (fast). The overall order of the reaction is:

The reaction of hydrogen and iodine monochloride is given as
$H_{2(g)} + 2ICl_{(g)} \to 2HCl_{(g)} + I_{2(g)}$
This reaction is of first order with respect to $H_{2(g)}$ and $ICl_{(g)}$. Which of the following mechanisms is consistent with the given information?
Mechanism $A$:
$H_{2(g)} + 2ICl_{(g)} \to 2HCl_{(g)} + I_{2(g)}$
Mechanism $B$:
$H_{2(g)} + ICl_{(g)} \to HCl_{(g)} + HI_{(g)}$ (Slow)
$HI_{(g)} + ICl_{(g)} \to HCl_{(g)} + I_{2(g)}$ (Fast)

The reaction,$X + 2Y + Z \to N$ occurs by the following mechanism:
$(i)$ $X + Y \rightleftharpoons M$ (very rapid equilibrium)
$(ii)$ $M + Z \to P$ (slow)
$(iii)$ $P + Y \to N$ (very fast)
What is the rate law for this reaction?

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Which of the following is an example of a second-order reaction?

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