For the reaction: $A_{(g)} + B_{(s)} \rightleftharpoons 2C_{(g)} + D_{(g)}$,given $\Delta U = 5.0 \ kcal$ and $\Delta S = 50 \ cal \ K^{-1}$ at $400 \ K$. Calculate $\Delta G$ for the reaction. (in $kcal$)

$18 \ g$ glucose is completely combusted in a bomb calorimeter of heat capacity $1400 \ kJ/K$. The temperature changes from $27 \ ^\circ C$ to $27.2 \ ^\circ C$. Calculate the magnitude of the standard enthalpy of combustion of glucose in $kJ/mol$. $[R = 8.314 \ J/mol-K]$

$A$ sample of $n$-octane $(1.14 \ g)$ was completely burnt in excess of oxygen in a bomb calorimeter,whose heat capacity is $5 \ kJ \ K^{-1}$. As a result of the combustion reaction,the temperature of the calorimeter increased by $5 \ K$. The magnitude of the heat of combustion of octane at constant volume is $.......... \ kJ \ mol^{-1}$ (nearest integer).

Standard entropies of $X_2$,$Y_2$ and $XY_3$ are $60$,$40$ and $50 \ J \ K^{-1} \ mol^{-1}$ respectively. For the reaction $\frac{1}{2} X_2 + \frac{3}{2} Y_2 \rightarrow XY_3$,the enthalpy change is $\Delta H = -30 \ kJ \ mol^{-1}$. At what temperature will the reaction be at equilibrium (in $K$)?

When $128 \, g$ of oxygen gas is heated from $0 \, ^oC$ to $100 \, ^oC$,the average values of $C_v$ and $C_p$ are $5 \, cal \, mol^{-1} \, K^{-1}$ and $7 \, cal \, mol^{-1} \, K^{-1}$ respectively. Find the values of $\Delta U$ and $\Delta H$.

$1 \ mol$ of $NH_3$ $(\gamma = 4/3)$ gas at $27 \ ^\circ C$ is expanded under reversible adiabatic conditions to make the volume $8$ times. Calculate the work done in $cal$.