The gas that cannot be collected over water is

$A$ volume of $x \ mL$ of $5 \ M \ NaHCO_3$ solution was mixed with $10 \ mL$ of $2 \ M \ H_2CO_3$ solution to make an electrolytic buffer. If the same buffer was used in the following electrochemical cell to record a cell potential of $235.3 \ mV$, then the value of $x = . . . . . . \ mL$ (nearest integer).
$Sn_{(s)} \mid Sn(OH)_6^{2-}(0.5 \ M) \mid HSnO_2^{-}(0.05 \ M) \mid OH^{-} \mid Bi_2O_{3(s)} \mid Bi_{(s)}$
Consider upto one place of decimal for intermediate calculations.

Given :	$E^{\circ}_{HSnO_2^{-} \mid Sn(OH)_6^{2-}} = -0.9 \ V$
	$E^{\circ}_{Bi_2O_3 \mid Bi} = -0.44 \ V$
	$pKa_{(H_2CO_3)} = 6.11$
	$\frac{2.303 \ RT}{F} = 0.059 \ V$
	$Antilog(1.29) = 19.5$

Two rectangular blocks,having identical dimensions,can be arranged either in configuration $I$ or in configuration $II$ as shown in the figure. One of the blocks has thermal conductivity $k$ and the other $2k$. The temperature difference between the ends along the $x-$ axis is the same in both the configurations. It takes $9 \ s$ to transport a certain amount of heat from the hot end to the cold end in the configuration $I$. The time to transport the same amount of heat in the configuration $II$ is .......... $\sec$.

Which concentrations can be calculated if the mole fraction and density of an aqueous solution of $HCl$ are known?
$1.$ Molality $\ \ 2.$ Molarity $\ \ 3.$ $\%(w/w)$

If $\frac{ax^2 + bx + c}{(x - 1)(x + 2)(2x + 3)} = \frac{3}{x - 1} + \frac{2}{x + 2} - \frac{5}{2x + 3}$,then:

The wavelengths of two sound notes in air are $\frac{40}{195} ~m$ and $\frac{40}{193} ~m$. Each note produces $9$ beats per second separately with a third note of fixed frequency. The velocity of sound in air in $m/s$ is