Given below are two statements: One is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: Permanganate titrations are not performed in the presence of hydrochloric acid.
Reason $R$: Chlorine is formed as a consequence of the oxidation of hydrochloric acid.
In the light of the above statements,choose the correct answer from the options given below.

  • A
    Both $A$ and $R$ are true and $R$ is the correct explanation of $A$.
  • B
    Both $A$ and $R$ are true but $R$ is $NOT$ the correct explanation of $A$.
  • C
    $A$ is true but $R$ is false.
  • D
    $A$ is false but $R$ is true.

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$A$ $2.0 \, g$ sample containing $MnO_2$ is treated with $HCl$ liberating $Cl_2$. The $Cl_2$ gas is passed into a solution of $KI$ and $60.0 \, mL$ of $0.1 \, M \, Na_2S_2O_3$ is required to titrate the liberated iodine. The percentage of $MnO_2$ in the sample is $.....$ (Nearest integer).
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