Given
$C_{(graphite)} + O_{2(g)} \rightarrow CO_{2(g)};$
$\Delta_rH^o = -393.5 \, kJ \, mol^{-1}$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O_{(l)};$
$\Delta_rH^o = -285.8 \, kJ \, mol^{-1}$
$CO_{2(g)} + 2H_2O_{(l)} \rightarrow CH_{4(g)} + 2O_{2(g)};$
$\Delta_rH^o = + 890.3 \, kJ \, mol^{-1}$
Based on the above thermochemical equations,the value of $\Delta_rH^o$ at $298 \, K$ for the reaction
$C_{(graphite)} + 2H_{2(g)} \rightarrow CH_{4(g)}$ will be ........... $kJ \, mol^{-1}$.

  • A
    $+ 74.8$
  • B
    $+ 144.0$
  • C
    $- 74.8$
  • D
    $- 144.0$

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$\Delta H^o_f$ of water is $-285.5 \, kJ \, mol^{-1}$. If enthalpy of neutralisation of monoacidic strong base is $-57.3 \, kJ \, mol^{-1}$,$\Delta H^o_f$ of $OH^{-}$ ion will be.....$kJ \, mol^{-1}$

Match the List-$I$ with List-$II$
List-$I$ Thermodynamic Process List-$II$ Magnitude in $kJ$
$A$. Work done in reversible, isothermal expansion of $2 \ mol$ of ideal gas from $2 \ dm^3$ to $20 \ dm^3$ at $300 \ K$. $I$. $4$
$B$. Work done in irreversible isothermal expansion of $1 \ mol$ ideal gas from $1 \ m^3$ to $3 \ m^3$ at $300 \ K$ against a constant pressure of $3 \ kPa$. $II$. $11.5$
$C$. Change in internal energy for adiabatic expansion of a $1 \ mol$ ideal gas with change of temperature $= 320 \ K$ and $\overline{C}_V = \frac{3}{2} R$. $III$. $6$
$D$. Change in enthalpy at constant pressure of $1 \ mole$ ideal gas with change of temperature $= 337 \ K$ and $\overline{C}_P = \frac{5}{2} R$. $IV$. $7$

Choose the correct answer from the option given below:

Calculate the enthalpy change when $50 \ mL$ of $0.01 \ M$ $Ca(OH)_2$ reacts with $25 \ mL$ of $0.01 \ M$ $HCl$. Given that $\Delta H^o$ for neutralization of a strong acid and a strong base is $-13.7 \ kcal \ mol^{-1}$. (Note: The provided value in the prompt $140 \ kcal \ mol^{-1}$ is physically incorrect for neutralization; using standard value $-13.7 \ kcal \ mol^{-1}$ for calculation). (in $kcal$)

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The heat evolved in the combustion of methane is given by the following equation: $CH_{4(g)} + 2O_{2(g)} \to CO_{2(g)} + 2H_2O_{(l)}$; $\Delta H = -890.3 \ kJ$. How many grams of methane would be required to produce $445.15 \ kJ$ of heat of combustion?

Standard entropies of $X_2$,$Y_2$ and $XY_3$ are $60$,$40$ and $50 \ J \ K^{-1} \ mol^{-1}$ respectively. For the reaction $\frac{1}{2} X_2 + \frac{3}{2} Y_2 \rightarrow XY_3$,the enthalpy change is $\Delta H = -30 \ kJ \ mol^{-1}$. At what temperature will the reaction be at equilibrium (in $K$)?

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