Heat of transition is the heat evolved or absorbed when a substance is converted from

Given
$N_{2(g)} + 3H_{2(g)} \longrightarrow 2NH_{3(g)} \quad \Delta_{r}H^{\theta} = -92.4 \, kJ \, mol^{-1}$
What is the standard enthalpy of formation of $NH_{3}$ gas?

The calorific value of hydrogen gas is $-143 \ kJ \ g^{-1}$. The standard enthalpy of formation of $H_2O$ will be $—$

The standard heat of formation,in $kcal / mol$ of $Ba^{2+}$ is
[Given : standard heat of formation of $SO_4^{2-}$ ion $(aq) = -216 \ kcal / mol$,
Standard heat of crystallisation of $BaSO_{4(s)} = -4.5 \ kcal / mol$,standard heat of formation of $BaSO_{4(s)} = -349 \ kcal / mol$]

If $S + O_2 \to SO_2; (\Delta H = -298.2 \ kJ)$,$SO_2 + \frac{1}{2} O_2 \to SO_3; (\Delta H = -98.2 \ kJ)$,$SO_3 + H_2O \to H_2SO_4; (\Delta H = -130.2 \ kJ)$,$H_2 + \frac{1}{2} O_2 \to H_2O; (\Delta H = -287.3 \ kJ)$,then the enthalpy of formation of $H_2SO_4$ at $298 \ K$ will be......$kJ$.

Based on the following thermochemical reactions:
$H_2O_{(g)} + C_{(s)} \rightarrow CO_{(g)} + H_{2(g)} ; \Delta H = 131 \ kJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \rightarrow CO_{2(g)} ; \Delta H = -282 \ kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_2O_{(g)} ; \Delta H = -242 \ kJ$
$C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)} ; \Delta H = x \ kJ$
The value of $x$ will be: