Heating chloroform with aqueous sodium hydrox | vedclass

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Question

(C) When chloroform $(CHCl_3)$ is heated with aqueous sodium hydroxide $(NaOH)$,it undergoes hydrolysis to form an unstable intermediate,methanetriol

Vedclass · Accepted Answer

sodium formate

Vedclass · Answer

(C) When chloroform $(CHCl_3)$ is heated with aqueous sodium hydroxide $(NaOH)$,it undergoes hydrolysis to form an unstable intermediate,methanetriol $(HC(OH)_3)$.This intermediate loses a water molecule to form formic acid $(HCOOH)$.Formic acid then reacts with the remaining $NaOH$ to produce sodium formate $(HCOONa)$.The overall reaction is: $CHCl_3 + 4NaOH \rightarrow HCOONa + 3NaCl + 2H_2O$.

Heating chloroform with aqueous sodium hydroxide solution forms

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