Identify from the following reactions the one that exhibits negative work done by the system.

  • A
    $2 H_2 O_{2(\ell)} \rightarrow 2 H_2 O_{(\ell)} + O_{2_{(g)}}$
  • B
    $NH_{3_{(g)}} + HCl_{(g)} \rightarrow NH_4 Cl_{(s)}$
  • C
    $H_{2_{(g)}} + Cl_{2_{(g)}} \rightarrow 2 HCl_{(g)}$
  • D
    $N_{2_{(g)}} + 3 H_{2_{(g)}} \rightarrow 2 NH_{3_{(g)}}$

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The change in internal energy equals

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Reason : Enthalpy change is always greater than internal energy change.

For water $\Delta_{vap} H = 41 \ kJ \ mol^{-1}$ at $373 \ K$ and $1 \ bar$ pressure. Assuming that water vapour is an ideal gas that occupies a much larger volume than liquid water,the internal energy change during evaporation of water is $...... \ kJ \ mol^{-1}$.
[Use: $R = 8.3 \ J \ mol^{-1} \ K^{-1}$]

What is the change in internal energy of the system when the work done by the system is $150 \ J$ and the system releases $300 \ J$ of heat?

$A$ mixture of $2 \ mol$ of $CO_{(g)}$ and $1 \ mol$ of $O_{2(g)}$ is ignited to convert $CO$ to $CO_2$. Which of the following relations is correct?

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