Identify the correct decreasing order of boiling points for the following organic compounds.

  • A
    Carboxylic acids > Amines > Alcohols
  • B
    Carboxylic acids > Alcohols > Amines
  • C
    Amines > Alcohols > Carboxylic acids
  • D
    Alcohols > Amines > Carboxylic acids

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When compound $X$ is oxidised by acidified potassium dichromate,compound $Y$ is formed. Compound $Y$ on reduction with $LiAlH_4$ gives $X$. $X$ and $Y$ respectively are:

$(i) \ F_3CCOOH$
$(ii) \ CH_3COOH$
$(iii) \ C_6H_5COOH$
$(iv) \ CH_3CH_2COOH$
Correct order of $pK_a$ value is:

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