Identify the correct decreasing order of stability of complexes formed by divalent metal ions with the same ligand.

  • A
    $Cu^{2+} > Mn^{2+} > Cd^{2+}$
  • B
    $Cd^{2+} > Mn^{2+} > Cu^{2+}$
  • C
    $Mn^{2+} > Cd^{2+} > Cu^{2+}$
  • D
    $Cu^{2+} > Cd^{2+} > Mn^{2+}$

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When $0.1 \ mole$ of $CoCl_3(NH_3)_5$ is treated with excess of $AgNO_3$,$0.2 \ mole$ of $AgCl$ are obtained. The conductivity of the solution will correspond to:

Ammonia forms the complex ion $[Cu(NH_3)_4]^{2+}$ with copper ions in alkaline solutions but not in acidic solution. What is the reason for it?

On treatment of $100 \ mL$ of $0.1 \ M$ solution of $CoCl_3 \cdot 6H_2O$ with excess $AgNO_3$,$1.2 \times 10^{22}$ ions are precipitated. The complex is:

Select the option containing the correct order of the given parameter.

$Ag^{+} + NH_3 \rightleftharpoons [Ag(NH_3)]^{+}$; $k_1 = 3.5 \times 10^{-3}$
$[Ag(NH_3)]^{+} + NH_3 \rightleftharpoons [Ag(NH_3)_2]^{+}$; $k_2 = 1.7 \times 10^{-3}$
Then the formation constant of $[Ag(NH_3)_2]^{+}$ is

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