Identify the correct statement$(s)$:

  • A
    The oxidation number of $Cr$ in $CrO_5$ is $+6$
  • B
    $\Delta H > \Delta U$ for the reaction $N_2O_{4(g)} \rightarrow 2NO_{2(g)}$, provided both gases behave ideally
  • C
    pH of $0.1 \ N \ H_2SO_4$ is less than that of $0.1 \ N \ HCl$ at $25^{\circ} C$
  • D
    $\left(\frac{2.303 RT}{F}\right) = 0.0591 \ V$ at $25^{\circ} C$

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Consider the following cell reaction:
$2Fe_{(s)} + O_{2(g)} + 4H^{+}_{(aq)} \to 2Fe^{2+}_{(aq)} + 2H_2O_{(l)}$; $E^o = 1.67 \ V$
At $[Fe^{2+}] = 10^{-3} \ M$,$p(O_2) = 0.1 \ atm$ and $pH = 3$,the cell potential at $25 \ ^oC$ is .............. $V$.

For the cell $Zn | Zn^{2+}(0.01 \, M) || Fe^{2+}(0.001 \, M) | Fe$ at $25^o C$,the $E_{cell} = 0.2905 \, V$. The equilibrium constant $K_c$ is:

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Calculate the $emf$ of the cell in which the following reaction takes place:
$Ni_{(s)} + 2Ag^{+}(0.002 \, M) \rightarrow Ni^{2+}(0.160 \, M) + 2Ag_{(s)}$
Given that $E^{\Theta}_{(cell)} = 1.05 \, V$ (in $, V$)

What pressure $(bar)$ of $H_2$ would be required to make the $emf$ of a hydrogen electrode zero in pure water at $25^{\circ} C$?

The potential of the cell for the reaction $M_{(s)} + 2H^{+}(1 \ M) \to H_2(1 \ atm) + M^{2+}(0.1 \ M)$ is $1.5 \ V$. The standard reduction potential for $M^{2+}/M_{(s)}$ couple is ............. $V$.

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