Identify the pair of complexes that exhibits | vedclass

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Question

(A) Solvate isomerism (also known as hydrate isomerism when water is the solvent) occurs when the solvent molecule acts as a ligand in one isomer and

Vedclass · Accepted Answer

$[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$

Vedclass · Answer

(A) Solvate isomerism (also known as hydrate isomerism when water is the solvent) occurs when the solvent molecule acts as a ligand in one isomer and as a lattice molecule (outside the coordination sphere) in another.In the pair $[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$,the first complex has $6$ water molecules as ligands,while the second has $5$ water molecules as ligands and $1$ water molecule as a lattice molecule.Therefore,this pair exhibits solvate isomerism.

List-$I$	List-$II$
$I. [FeF_6]^{3-}$	$A. 1.73 \ BM$
$II. [Ti(H_2O)_6]^{3+}$	$B. 5.93 \ BM$
$III. [Cr(NH_3)_6]^{3+}$	$C. 0.00 \ BM$
$IV. [Ni(H_2O)_6]^{2+}$	$D. 2.83 \ BM$
$V. [Fe(CN)_6]^{4-}$	$E. 3.88 \ BM$

Identify the pair of complexes that exhibits solvate isomerism.

Similar Questions

Which of the following complexes exhibit geometrical isomerism?
$I$) $[Co(en)(NH_3)_2 Cl_2] Cl$
$II$) $[Co(NH_3)_4 Cl_2] Cl$
$III$) $[Co(en)_3] Cl_3$
$IV$) $[Co(en)_2 Cl_2] Br$

Which of the following is diamagnetic in nature?

The complex that can exhibit linkage isomerism is

Match List-$I$ with List-$II$ and select the correct answer using the codes given below:
List-$I$ List-$II$
$I. [FeF_6]^{3-}$ $A. 1.73 \ BM$
$II. [Ti(H_2O)_6]^{3+}$ $B. 5.93 \ BM$
$III. [Cr(NH_3)_6]^{3+}$ $C. 0.00 \ BM$
$IV. [Ni(H_2O)_6]^{2+}$ $D. 2.83 \ BM$
$V. [Fe(CN)_6]^{4-}$ $E. 3.88 \ BM$

$[Co(NH_3)_5SO_4]Br$ and $[Co(NH_3)_5Br]SO_4$ are a pair of which isomers?

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