If $20 \ mL$ of $0.1 \ M \ NaOH$ is added to $30 \ mL$ of $0.2 \ M \ CH_3COOH$ $(pK_a = 4.74)$,the $pH$ of the resulting solution is

  • A
    $4.44$
  • B
    $9.56$
  • C
    $8.96$
  • D
    $9.26$

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Aqueous solutions of $HNO_{3}$, $KOH$, $CH_{3}COOH$, and $CH_{3}COONa$ of identical concentration are provided. The pair$(s)$ of solutions which form a buffer upon mixing is (are):

$A$ litre of buffer solution contains $0.1 \ mol$ of each of $NH_3$ and $NH_4Cl$. On the addition of $0.02 \ mol$ of $HCl$ by dissolving gaseous $HCl$,the $pH$ of the solution is found to be $...... \times 10^{-3}$ (Nearest integer).
Given: $pK_b(NH_3) = 4.745$,$\log 2 = 0.301$,$\log 3 = 0.477$,$T = 298 \ K$.

$A$ buffer solution is prepared with a concentration of $0.30 \ M \ NH_3$ and $0.20 \ M \ NH_4^+$. If the equilibrium constant for $NH_3$ is $K_b = 1.8 \times 10^{-5}$,what will be the $pH$ of this solution?

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