If the cell potential of the cell at $298 \ K$ is $2.36 \ V$,write the cell reaction and calculate the standard electrode potential of the $Mg^{2+} \mid Mg$ half-cell.
$Mg_{(s)} \mid Mg^{2+}_{(1 \ M)} \parallel H^{+}_{(1 \ M)} \mid H_{2(g)} (1 \ bar) \mid Pt_{(s)}$

  • A
    Anode: $Mg \rightarrow Mg^{2+} + 2e^-$,Cathode: $2H^+ + 2e^- \rightarrow H_2$,$E^\circ_{Mg^{2+}/Mg} = -2.36 \ V$
  • B
    Anode: $Mg \rightarrow Mg^{2+} + 2e^-$,Cathode: $2H^+ + 2e^- \rightarrow H_2$,$E^\circ_{Mg^{2+}/Mg} = +2.36 \ V$
  • C
    Anode: $Mg^{2+} + 2e^- \rightarrow Mg$,Cathode: $H_2 \rightarrow 2H^+ + 2e^-$,$E^\circ_{Mg^{2+}/Mg} = -2.36 \ V$
  • D
    Anode: $Mg \rightarrow Mg^{2+} + 2e^-$,Cathode: $2H^+ + 2e^- \rightarrow H_2$,$E^\circ_{Mg^{2+}/Mg} = -1.18 \ V$

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Similar Questions

Give the symbolic representation of the following half-cells (electrodes):
$(i)$ $Zn_{(s)} | Zn^{2+}_{(aq)} (1M)$
$(ii)$ $Cu^{2+}_{(aq)} (1M) | Cu_{(s)}$
$(iii)$ $Pt_{(s)} | H_{2(g)} (1 \text{ bar}) | H^+_{(aq)} (1M)$

The oxidation potentials of $Zn, Cu, Ag, H_2$ and $Ni$ are $0.76, -0.34, -0.80, 0$ and $0.25 \ V$ respectively. Which reaction provides the maximum voltage?

At $25^\circ C$,$1 \, atm$ of gas $X$ is bubbled through a solution containing $1 \, M$ $Y^-$ and $1 \, M$ $Z^-$. If the reduction potential order is $Z > Y > X$,then:

The standard electrode potentials are: $K^{+}/K = -2.93 \ V$,$Ag^{+}/Ag = 0.80 \ V$,$Hg^{2+}/Hg = 0.79 \ V$,$Mg^{2+}/Mg = -2.37 \ V$,$Cr^{3+}/Cr = -0.74 \ V$. Arrange these metals in the increasing order of their reducing power.

The standard reduction potentials at $298 \ K$ for the following half reactions are given against each:
$Zn^{2+}(aq.) + 2e^- \rightleftharpoons Zn_{(s)}$; $E^\circ = -0.762 \ V$
$Cr^{3+}(aq.) + 3e^- \rightleftharpoons Cr_{(s)}$; $E^\circ = -0.740 \ V$
$2H^{+}(aq.) + 2e^- \rightleftharpoons H_{2(g)}$; $E^\circ = 0.00 \ V$
$Fe^{3+}(aq.) + e^- \rightleftharpoons Fe^{2+}(aq.)$; $E^\circ = 0.770 \ V$
Which is the strongest reducing agent?

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