If the internuclear axis is the $z$-axis,then in which of the following cases are $\sigma$ and $\pi$ bonds not possible?

Match the orbital overlap figures shown in List-$I$ with the description given in List-$II$ and select the correct answer using the code given below the lists.
List-$I$:
$P$. Two $d$-orbitals overlapping axially with same phase.
$Q$. $A$ $p$-orbital and a $d$-orbital overlapping laterally with same phase.
$R$. $A$ $p$-orbital and a $d$-orbital overlapping laterally with opposite phase.
$S$. Two $d$-orbitals overlapping axially with opposite phase.
List-$II$:
$1$. $p-d$ $\pi$ antibonding
$2$. $d-d$ $\sigma$ bonding
$3$. $p-d$ $\pi$ bonding
$4$. $d-d$ $\sigma$ antibonding
Codes: $P \quad Q \quad R \quad S$

The total number of sigma $(\sigma)$ and pi $(\pi)$ bonds in an ethylene molecule are

$A$ molecule $(X)$ has $(i)$ four sigma bonds formed by the overlap of $sp^2$ and $s$ orbitals,(ii) one sigma bond formed by $sp^2$ and $sp^2$ orbitals,and (iii) one $\pi$ bond formed by $p_z$ and $p_z$ orbitals. Which of the following is $X$?

The nodal plane of the $\pi$-bond in ethene is located in:

The fluorine molecule is formed by