If standard molar enthalpy change and standard molar internal energy change measured in a bomb calorimeter are equal,which one of the following statements is correct?
- A$ \Delta n > 0 $,with increase in pressure
- B$ \Delta n > 0 $,with decrease in pressure
- C$ \Delta n < 0 $,with increase in pressure
- D$ \Delta n = 0 $,at constant pressure
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Calculate the standard internal energy change for $OF_{2(g)} + H_2O_{(g)} \longrightarrow 2 HF_{(g)} + O_{2(g)}$ at $300 \ K$,if $\Delta_{f} H^{\circ}$ of $OF_{2(g)}$,$H_2O_{(g)}$,and $HF_{(g)}$ are $20$,$-250$,and $-270 \ kJ \ mol^{-1}$ respectively. $[R = 8.314 \ J \ K^{-1} \ mol^{-1}]$ (in $kJ$)
Two liters of $N_2$ gas at $0 \, ^\circ C$ and $5 \, atm$ pressure undergoes isothermal expansion against a constant external pressure of $1 \, atm$ until the pressure of the gas becomes $1 \, atm$. If the gas is ideal,what is the work done in the expansion in $J$?
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View SolutionAt $300 \ K$, $3.0 \ \text{moles}$ of an ideal gas at $3.0 \ \text{atm}$ pressure is compressed isothermally to one half of its volume by an external pressure of $6.0 \ \text{atm}$. The work done (in $kJ$) is. Given, $R=0.082 \ \text{L atm K}^{-1} \text{mol}^{-1}$ $(1 \ \text{L atm} = 101.3 \ \text{J})$.
An ideal gas undergoes isothermal compression from $5\, m^3$ to $1\, m^3$ against a constant external pressure of $4\, Nm^{-2}$. Heat released in this process is used to increase the temperature of $1\, mole$ of $Al$. If molar heat capacity of $Al$ is $24\, J\, mol^{-1}\, K^{-1}$,the temperature of $Al$ increases by:
For the reaction at $300 \, K$,$A_{(g)} + B_{(g)} \to C_{(g)}$,given $\Delta U = -3 \, kcal$ and $\Delta S = -10 \, cal/K$. The value of $\Delta G$ will be $...... \, cal$.
Medium
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