In a particular reaction, $4 \text{ kJ}$ of heat is released by the system and $12 \text{ kJ}$ of work is done on the system. Calculate the $\Delta H$ and $\Delta U$.

  • A
    $\Delta H = 4 \text{ kJ}$ and $\Delta U = 16 \text{ kJ}$
  • B
    $\Delta H = -4 \text{ kJ}$ and $\Delta U = 8 \text{ kJ}$
  • C
    $\Delta H = -4 \text{ kJ}$ and $\Delta U = -16 \text{ kJ}$
  • D
    $\Delta H = 4 \text{ kJ}$ and $\Delta U = -16 \text{ kJ}$

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For the reaction $N_2(g) + 3H_2(g) \rightarrow 2NH_3(g)$ at constant temperature and pressure,if $\Delta H$ and $\Delta U$ are the enthalpy and internal energy changes for the reaction,which of the following equations is correct?

Work done in vaporisation of one mole of water at $373 \ K$ and the pressure of $1 \ atm$ is approximately (for ideal gas)......$J$

Two moles of an ideal monoatomic gas are allowed to expand adiabatically and reversibly from $300 \ K$ to $200 \ K$. The work done in the system is $... \ kJ$ $(C_V = 12.5 \ J/K/mol)$.

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Reason : Enthalpy change is always greater than internal energy change.

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