In an estimation of sulphur by Carius method, $0.2 \text{ g}$ of the substance gave $0.6 \text{ g}$ of $BaSO_4$. The percentage of sulphur in the substance is . . . . . . %. (Given molar mass in $\text{g mol}^{-1}$: $S = 32$, $BaSO_4 = 233$)

  • A
    $41$
  • B
    $45$
  • C
    $48$
  • D
    $50$

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Which of the following is a $FALSE$ statement?

How much $\%$ sulphur is present in an organic compound if on analysis $0.53 \ g$ of this compound gives $1.158 \ g$ of $BaSO_4$ (in $\%$)?

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Match Column-$I$ and Column-$II$ with the correct relation:
Column-$I$ Column-$II$
$(i).$ Magnesium pyrophosphate $(a).$ $I_2O_5$
$(ii).$ Barium sulphate $(b).$ $AgX$
$(iii).$ Iodide pentoxide $(c).$ $Mg_2P_2O_7$
$(iv).$ Silver halide $(d).$ $BaSO_4$

Fill in the blanks:
$(1)$ ........... solution is added to produce the precipitate of $BaSO_4$ in the estimation of sulphur.
$(2)$ .......... and .... precipitate will be produced by the estimation of phosphorus.
$(3)$ How many elements are estimated in organic compounds?
$(4)$ ......... gas is produced in the Dumas method,but ....... gas is produced in the Kjeldahl's method.

The transformation occurring in Dumas's method is given below:
$C_{2}H_{7}N + (2x + \frac{y}{2})CuO \rightarrow xCO_{2} + \frac{y}{2}H_{2}O + \frac{z}{2}N_{2} + (2x + \frac{y}{2})Cu$
The value of $y$ is ...... .(Integer answer)

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