In a Carius tube,an organic compound '$X$' is treated with sodium peroxide to form a mineral acid '$Y$'. The solution of $BaCl_2$ is added to '$Y$' to form a precipitate '$Z$'. '$Z$' is used for the quantitative estimation of an extra element. '$X$' could be:

Given below are two statements :
Statement $I$ : Kjeldahl method is applicable to estimate nitrogen in pyridine.
Statement $II$ : The nitrogen present in pyridine can easily be converted into ammonium sulphate in Kjeldahl method.
In the light of the above statements,choose the correct answer from the options given below.

$0.53 \ g$ of an organic compound $(x)$ when heated with excess of nitric acid (concentrated) and then with silver nitrate gave $0.75 \ g$ of silver bromide precipitate. $1.0 \ g$ of $(x)$ gave $1.32 \ g$ of $CO_2$ gas on combustion. The percentage of hydrogen in the compound $(x)$ is . . . . . . $\%$. [Nearest Integer]
[Given : Molar mass in $g \ mol^{-1} H : 1, C : 12, Br : 80, Ag : 108, O : 16$; Compound $(x) : C_xH_yBr_z$] (in $\%$)

In Dumas method for the estimation of $N_2$,the sample is heated with copper oxide and the gas evolved is passed over :

In the Carius method,a halogen-containing organic compound is heated with fuming nitric acid in the presence of:

In the Dumas method,$1 \ g$ of an organic compound gives $50 \ mL$ of $N_2$ gas at $300 \ K$ and $740 \ mm \ Hg$ pressure. If the aqueous tension at $300 \ K$ is $15 \ mm \ Hg$,what is the percentage of nitrogen in the compound?