In Dumas' method for estimation of nitrogen,$0.3 \ g$ of an organic compound gave $50 \ mL$ of nitrogen collected at $300 \ K$ temperature and $715 \ mm$ pressure. Calculate the percentage composition of nitrogen in the compound. (Aqueous tension at $300 \ K = 15 \ mm$)

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The pressure of dry nitrogen is $P_{N_2} = P_{total} - P_{aqueous} = 715 \ mm - 15 \ mm = 700 \ mm$.
Using the combined gas law to convert the volume to $STP$ ($273 \ K$ and $760 \ mm$):
$V_{STP} = \frac{P_{N_2} \times V \times 273}{P_{STP} \times T} = \frac{700 \times 50 \times 273}{760 \times 300} \approx 41.91 \ mL$.
Since $22,400 \ mL$ of $N_2$ at $STP$ weighs $28 \ g$,the mass of $N_2$ is:
$Mass_{N_2} = \frac{28 \times 41.91}{22400} \approx 0.05239 \ g$.
Percentage of nitrogen $= \frac{Mass_{N_2}}{Mass_{compound}} \times 100 = \frac{0.05239}{0.3} \times 100 \approx 17.46 \%$.

Explore More

Similar Questions

$29.5 \ mg$ of an organic compound containing nitrogen was digested according to Kjeldahl's method and the evolved ammonia was absorbed in $20 \ mL$ of $0.1 \ M \ HCl$ solution. The excess of the acid required $15 \ mL$ of $0.1 \ M \ NaOH$ solution for complete neutralization. The percentage of nitrogen in the compound is $..... \%$.

Which formula is used in the Kjeldahl method for the estimation of nitrogen?

In the Carius method for the estimation of halogen,$0.172 \ g$ of an organic compound showed the presence of $0.08 \ g$ of bromine. Which of these is the correct structure of the compound?

When $1 \ g$ of compound $(X)$ is subjected to Kjeldahl's method for the estimation of nitrogen, $15 \ mL$ of $1 \ M$ $H_2SO_4$ was neutralized by the ammonia evolved. The percentage of nitrogen in compound $(X)$ is:

In the estimation of bromine,$0.5 \ g$ of an organic compound gave $0.40 \ g$ of silver bromide. The percentage of bromine in the given compound is $..... \ \%$ (nearest integer).
(Relative atomic masses of $Ag$ and $Br$ are $108 \ u$ and $80 \ u$,respectively).

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo