In the Kjeldahl method,$0.35 \ g$ of an organic compound produces ammonia,which is absorbed in $100 \ mL$ of $0.1 \ M \ H_2SO_4$. The excess $H_2SO_4$ requires $154 \ mL$ of $0.1 \ M \ NaOH$ for titration. Calculate the percentage of nitrogen in the compound. (Given atomic masses: $C=12, H=1, O=16, N=14, S=32$)

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) $1$. Calculate the total millimoles of $H_2SO_4$ taken: $100 \ mL \times 0.1 \ M = 10 \ mmol$.
$2$. Since $H_2SO_4$ is a dibasic acid,the milliequivalents of $H_2SO_4$ are $10 \ mmol \times 2 = 20 \ meq$.
$3$. Calculate the milliequivalents of $NaOH$ used for titration: $154 \ mL \times 0.1 \ M = 15.4 \ meq$.
$4$. The milliequivalents of $H_2SO_4$ consumed by $NH_3$ are $20 \ meq - 15.4 \ meq = 4.6 \ meq$.
$5$. Since $1 \ meq$ of $NH_3$ contains $1 \ mmol$ of $N$,the mass of nitrogen is $4.6 \ mmol \times 14 \ g/mol = 64.4 \ mg = 0.0644 \ g$.
$6$. The percentage of nitrogen is $\frac{0.0644 \ g}{0.35 \ g} \times 100 = 18.4 \%$.

Explore More

Similar Questions

The number of moles of $CuO$ that will be utilized in the Dumas method for the estimation of nitrogen in a sample of $57.5 \ g$ of $N,N$-dimethylaminopentane is $..... \times 10^{-2}$. (Nearest integer)

Consider the following reaction. On estimation of bromine in $1.00 \ g$ of $R$ using Carius method,the amount of $AgBr$ formed (in $g$) is . . . .
$\overline{[Given :}$ Atomic mass of $H = 1, C = 12, O = 16, P = 31, Br = 80, Ag = 108]$

In the Dumas method,$1 \ g$ of an organic compound gives $50 \ mL$ of $N_2$ gas at $300 \ K$ and $740 \ mm \ Hg$ pressure. If the aqueous tension at $300 \ K$ is $15 \ mm \ Hg$,what is the percentage of nitrogen in the compound?

Kjeldahl's method was used for the estimation of nitrogen in an organic compound. The ammonia evolved from $0.55 \ g$ of the compound neutralized $12.5 \ mL$ of $1 \ M \ H_2SO_4$ solution. The percentage of nitrogen in the compound is $.....$ (Nearest integer).

Which element is estimated by the Carius method?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo