In the Kjeldahl's method for estimation of nitrogen present in a soil sample,ammonia evolved from $0.75 \ g$ of sample neutralized $10 \ mL$ of $1 \ M \ H_2SO_4$. The percentage of nitrogen in the soil is (in $.33$)

Match Column-$I$ and Column-$II$ with the correct relation:

Column-$I$	Column-$II$
$(i).$ Magnesium pyrophosphate	$(a).$ $I_2O_5$
$(ii).$ Barium sulphate	$(b).$ $AgX$
$(iii).$ Iodide pentoxide	$(c).$ $Mg_2P_2O_7$
$(iv).$ Silver halide	$(d).$ $BaSO_4$

Differentiate between the principle of estimation of nitrogen in an organic compound by $(i)$ Dumas method and $(ii)$ Kjeldahl's method.

In the estimation of sulphur by Carius method,$0.468 \,g$ of an organic sulphur compound afforded $0.668 \,g$ of barium sulphate. Find out the percentage of sulphur in the given compound. (in $\%$)

An organic compound is subjected to chlorination to get compound $A$. When $0.5 \ g$ of compound $A$ is reacted with $AgNO_3$ [Carius Method],it forms $0.3849 \ g$ of $AgCl$. Calculate the percentage of chlorine in compound $A$. (Round off to the nearest integer)
(Atomic masses of $Ag$ and $Cl$ are $107.87$ and $35.5$ respectively)

$0.3 \ g$ of an organic compound gave $50 \ mL$ of nitrogen collected at $300 \ K$ and $715 \ mm$ pressure in Dumas method. Calculate the percentage of nitrogen in the compound (aqueous tension of water at $300 \ K$ is $15 \ mm$).