In which of the following conditions will the reduction potential of a hydrogen half-cell be negative?

The half-cell reaction involving the quinhydrone electrode is shown below:
$HO-C_6H_4-OH_{(aq)} \rightleftharpoons O=C_6H_4=O_{(aq)} + 2H^+ + 2e^-$
If $E_{op}^o$ for this electrode is $1.30 \ V$,then what will be the oxidation electrode potential at $pH = 3$? ............ $V$

Calculate the equilibrium constant for the following reaction: $Ni_{(s)} + Cu_{(aq)}^{2+} \to Cu_{(s)} + Ni_{(aq)}^{2+}$. Given: $E_{Ni^{2+}|Ni}^o = -0.25 \ V$ and $E_{Cu^{2+}|Cu}^o = 0.34 \ V$.

The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. $A$ simple model for such a concentration cell involving a metal $M$ is:
$M_{(s)} \mid M^{+}(aq; 0.05 \ M) \parallel M^{+}(aq; 1 \ M) \mid M_{(s)}$
For the above electrolytic cell the magnitude of the cell potential $|E_{cell}|=70 \ mV$.
$1.$ For the above cell
$(A)$ $E_{cell} < 0 ; \Delta G > 0$ $(B)$ $E_{cell} > 0 ; \Delta G < 0$
$(C)$ $E_{cell} < 0 ; \Delta G^{\circ} > 0$ $(D)$ $E_{cell} > 0 ; \Delta G^{\circ} > 0$
$2.$ If the $0.05 \ M$ solution of $M^{+}$ is replaced by $0.0025 \ M$ $M^{+}$ solution,then the magnitude of the cell potential would be
$(A)$ $35 \ mV$ $(B)$ $70 \ mV$ $(C)$ $140 \ mV$ $(D)$ $700 \ mV$
Give the answer for questions $1$ and $2$.

What is the value of $E_{cell}$ at $298 \ K$ for the reaction,$Zn_{(s)} + Cu^{+2}(0.1 \ M) \rightarrow Zn^{+2}(0.1 \ M) + Cu_{(s)}$ if $E^{\circ}_{cell} = 1.1 \ V$ (in $V$)?

At $298 \ K$ the equilibrium constant for the reaction $M_{(s)} + 2 Ag^{+}_{(aq)} \rightarrow M^{2+}_{(aq)} + 2 Ag_{(s)}$ is $10^{15}$. What is the $E_{cell}^{\ominus}$ (in $V$) for this reaction? $\left(\frac{2.303 RT}{F}\right) = 0.06 \ V$